Research Directions

二维、多维相关光谱方法学研究及应用


通过正交样品设计的手段,发展二维相关光谱新方法,用于研究表征不同分子之间的相互作用,揭示分子间相互作用所导致的物质光谱的细微变化。为深化认识分子间相互作用的物理化学本质奠定基础。
发展二维及高维相关光谱新方法,对混合物样品的色谱-光谱联用数据进行分析,以获得通过色谱未能完全分离的体系中各成分的光谱。为解决复杂混合物样品的分析问题提供新方法。

复合氧化物颜料/尼龙6纳米复合彩色纤维材料研究


结合纳米技术,研发一类以稳定氧化物为基质,通过掺杂少量过渡金属离子呈色的、化学性质稳定、无毒无害、环境友好的新型复合氧化物颜料。并将其应用于无水印染,生产彩色纤维,为解决纺织印染工业的污水污染问题提供解决方案。

超浓酸体系的应用研究


通过反相胶束构建具有特殊物理化学性质的微环境,并以之为基质,发展制备超浓盐酸、超浓硝酸的新方法(超浓盐酸、超浓硝酸的浓度是常规饱和盐酸、硝酸的数十倍)。深化研究超浓盐酸、超浓硝酸的形成机理和物理化学性质。开发超浓盐酸、超浓硝酸在化学反应上的应用。

Theses

二维相关光谱

  • Li XP, He AQ, Huang K, Liu HZ, Zhao Y, Wei YJ, Xu YZ*, Noda I and Wu JG,
    Two-dimensional asynchronous spectrum with auxiliary cross peaks in probing intermolecular interactions, RSC Advances , 2015, 5, 87739–87749.

  • Chen J, Bi Q, Liu SX, Li XP, Liu YH, Zhai YJ, Zhao Y, Yang LM, Xu YZ*, Noda I and Wu JG,
    Double asynchronous orthogonal sample design scheme for probing intermolecular interactions, Journal of Physical Chemistry A , 2012, 116, 10904-10916.

  • Li XP, Pan QH, Chen J, Liu SX, He AQ, Liu CG, Wei YJ, Huang K, Yang LM, Feng J, Zhao Y, Xu YZ*, Ozaki Y, Noda I and Wu JG,
    Asynchronous orthogonal sample design scheme for two-dimensional correlation spectroscopy (2D-COS) and its application in probing intermolecular interactions from overlapping infrared (IR) bands, Applied Spectroscopy, 2011, 65, 901-917.

  • Zhang CF, Huang K, Li HZ, Chen J, Liu SX, Zhao Y, Wang DJ, Xu YZ*, Wu JG, Noda I and Ozaki Y,
    Double orthogonal sample design scheme and corresponding basic patterns in two-dimensional correlation spectra for probing subtle spectral variations caused by intermolecular interactions, Journal of Physical Chemistry A, 2009, 113, 12142-12156.

  • Liu YH, Zhang CF, Liu SX, Zhao Y, Wang DJ, Wu JG, Xu YZ* and Noda I,
    Modified orthogonal sample design scheme to probe intermolecular interactions, Journal of Molecular Structure, 2008, 883, 124-128.

  • Qi J, Li HZ, Huang K, Chen HH, Liu SX, Yang LM, Zhao Y, Zhang CF, Li WH, Wu JG, Xu DF, Xu YZ* and Noda I,
    Orthogonal sample design scheme for two-dimensional synchronous spectroscopy and its application in probing intermolecular interactions, Applied Spectroscopy, 2007, 61, 1359-1365.

    超浓酸体系

  • Guo R, Guo L, Huang K, He AQ, Zhang J, Zheng LR, Liu Y, Kang TG, Gao XX, Weng SF, Zhao Y, Yang ZL, Xu YZ*, Noda I and Wu JG,
    Investigation on the trioctylphosphine oxide-based super-concentrated HCl system, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015, 136, 288–294.

  • Huang K, Zhou H, He AQ, Sun Y, Liu YF, Gao XX, Zhao Y, Liu SX, Li ZH, Hu TD, Li XP, Liu CG, Wei YJ, Yang LM, Feng J, Cai YL, Yang ZL, Xu YZ*, Noda I and Wu JG,
    Superconcentrated hydrochloric acid, Journal of Physical Chemistry B, 2013, 115, 7823-7829.

    尼龙彩色纤维材料

  • Liu SX, Zhang CF, Proniewicz E, Proniewicz LM, Kim YK, Liu J, Zhao Y, Xu YZ* and Wu JG, Crystalline transition and morphology variation of polyamide 6/CaCl2 composite during the decomplexation process, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2013, 115, 783-788.

  • Li HZ, Wu YJ, Sato H, Kong L, Zhang CF, Huang K, Tao DL, Chen J, Liu XX, Zhao Y, Xu YZ*,
    Wu JG and Ozaki Y, A new facile method for preparation of Nylon-6 with high crystallinity and special morphology, Macromolecules, 2009, 42, 1175-1179.

    其他

  • Jiang Y, Kang XY, Gao DQ, He AQ, Guo R, Fan XK, Zhai YJ, Xia JM, Xu YZ*, Noda I and Wu JG,
    Finding a suitable separation condition for TLC/FTIR analysis by using multiple-narrow-band TLC technique, RSC Advances, 2015, 5, 21544-21549.(薄层色谱-红外联用)

  • Gao XX, Liu YF, Li HZ, Bian J, Zhao Y, Cao Y, Mao YZ, Li X, Xu YZ*,
    Ozaki Y and Wu JG, A cooperative hydrogen bonding system with a C-H…O hydrogen bond in ofloxacin, Journal of Molecular Structure, 2013, 1040, 122-128.(荧光)